Hastelloy C-276
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Hastelloy C-276

Supreme Corrosion Resistance • Chemical Processing Workhorse • Versatile Performance

Hastelloy C-276 is a nickel-molybdenum-chromium superalloy with exceptional resistance to a wide variety of chemical process environments, including strong oxidizers, chlorides, solvents, and acids. Renowned as the premier material for the most severe corrosive conditions, it combines outstanding versatility with resistance to pitting, crevice corrosion, and stress corrosion cracking.

Chemical Processing Extreme Corrosion Sour Gas Service Pollution Control

Quick Specifications

UNS Number: N10276
ASTM: B575, B619
EN: 2.4819
Density: 8.89 g/cm³
Melting Point: 1323-1371°C
Magnetic: No
690
Tensile Strength (MPa)
283
Yield Strength (MPa)
40%
Elongation
PREN 70+
Pitting Resistance
D
Machinability

Properties & Characteristics

Material Overview

Hastelloy C-276 is a solid-solution strengthened nickel-molybdenum-chromium alloy with excellent resistance to both oxidizing and reducing environments. Its high molybdenum content provides exceptional resistance to pitting and crevice corrosion, while chromium offers resistance to oxidizing media. The low carbon content minimizes carbide precipitation during welding, maintaining corrosion resistance in welded structures.

Key Benefits

Unmatched Versatility: Resists oxidizing, reducing, and mixed acid environments
Superior Pitting Resistance: Exceptional resistance to chloride-induced pitting and crevice corrosion
Weld Zone Protection: Low carbon prevents carbide precipitation in heat-affected zones
Stress Corrosion Immunity: Outstanding resistance to chloride stress corrosion cracking
Wide Temperature Range: Performs from cryogenic to elevated temperatures
Process Flexibility: Suitable for various fabrication and forming operations

Chemical Processing Excellence

Hastelloy C-276 is the industry standard for chemical processing equipment due to its exceptional resistance to a broad spectrum of corrosive chemicals. It performs reliably in environments containing sulfuric acid, hydrochloric acid, phosphoric acid, acetic acid, and numerous other aggressive media. The alloy's resistance to both oxidizing and reducing conditions makes it uniquely versatile.

Limitations

Challenging Machinability: Work hardens rapidly; requires specialized tooling and techniques
Premium Cost: High nickel and molybdenum content results in significant material expense
Lower Strength: Moderate strength compared to precipitation-hardened nickel alloys

Chemical Composition

Element Weight % Purpose
Nickel (Ni) Balance (57% min) Base metal, provides ductility and corrosion resistance
Molybdenum (Mo) 15.0 - 17.0 Superior pitting and crevice corrosion resistance
Chromium (Cr) 14.5 - 16.5 Oxidizing environment resistance and passivation
Tungsten (W) 3.0 - 4.5 Enhances corrosion resistance in reducing conditions
Iron (Fe) 4.0 - 7.0 Contributes to solid solution strengthening
Cobalt (Co) ≤ 2.5 Minor constituent (impurity limit)
Manganese (Mn) ≤ 1.0 Deoxidizer and sulfur control
Vanadium (V) ≤ 0.35 Grain refinement
Silicon (Si) ≤ 0.08 Deoxidizer (kept low)
Carbon (C) ≤ 0.01 Ultra-low to prevent sensitization

Chemistry Advantage: The high molybdenum (15-17%) combined with chromium and tungsten creates synergistic corrosion resistance superior to alloys with higher individual element contents. Ultra-low carbon (≤0.01%) ensures weld zone corrosion resistance without heat treatment.

Mechanical Properties (Solution Annealed)

Property Metric Imperial
Tensile Strength (Ultimate) 690 MPa 100,000 psi
Yield Strength (0.2% offset) 283 MPa 41,000 psi
Elongation at Break 40% (in 50mm)
Modulus of Elasticity 205 GPa 29.8 × 10⁶ psi
Rockwell Hardness ≤ 22 HRC (typical)
Brinell Hardness ≤ 223 HB
Shear Strength 400 MPa 58,000 psi
Shear Modulus 78.6 GPa 11.4 × 10⁶ psi
Poisson's Ratio 0.306

Note: Properties shown are for solution annealed condition. The alloy can be significantly strengthened by cold working. High ductility (40% elongation) provides excellent formability.

Physical Properties

Density
8.89 g/cm³
0.321 lb/in³
Melting Point
1323-1371°C
2415-2500°F
Maximum Service Temperature
1040°C
1900°F (oxidizing)
Thermal Conductivity
10.0 W/m-K
@ 24°C
Coefficient of Thermal Expansion
11.3 µm/m-K
20-100°C
Electrical Resistivity
1250 nΩ-m
@ 20°C
Specific Heat Capacity
427 J/kg-K
@ 24°C
PREN (Pitting Resistance)
70+
Cr + 3.3Mo + 16N

Industry Applications

Chemical Processing

Reaction vessels, heat exchangers, evaporators, transfer piping, valves, pumps, flue gas scrubbers, acetic acid production, pesticide production, chlorination systems, phosphoric acid production, sulfuric acid coolers, and equipment handling mixed acid environments.

Pollution Control & Environmental

Flue gas desulfurization (FGD) systems, wet scrubber components, stack gas reheaters, ducting, dampers, absorber vessels, spray nozzles, mist eliminators, and waste treatment equipment handling acidic and chloride-bearing solutions.

Oil & Gas / Petrochemical

Sour gas service components, sulfur recovery plants, hydrodesulfurization reactors, acid gas injection systems, geothermal wells, offshore drilling equipment, subsea wellhead components, and high-pressure high-temperature (HPHT) applications.

Pharmaceutical & Biotechnology

Process vessels, piping systems, pharmaceutical production equipment, bioreactors, fermentation tanks, clean-in-place (CIP) systems, and equipment requiring high purity and corrosion resistance.

Pulp & Paper

Digesters, bleach plant equipment, evaporators, flash tanks, liquor heaters, and components exposed to chlorine dioxide, hypochlorite, and acidic chloride solutions.

Waste Treatment

Hazardous waste incineration systems, radioactive waste processing, toxic waste neutralization equipment, and waste treatment facilities handling aggressive chemical mixtures.

CNC Machining Guidelines

D
Machinability Rating
Difficult - Extreme work hardening requires expert machining

Critical Machining Challenges

  • Rapid Work Hardening: Material hardens significantly under cutting pressure
  • Abrasive Nature: High molybdenum content is aggressive on cutting tools
  • Poor Thermal Conductivity: Heat concentrates at the tool-work interface
  • Gummy Chips: Tends to form long, stringy chips that wrap around tools
  • Built-Up Edge: Material can weld to cutting tool, degrading surface finish

Essential Best Practices

  • • Use coated carbide or ceramic tools only
  • • Maintain constant positive feed - NEVER dwell
  • • High-pressure coolant application mandatory
  • • Sharp tools essential - change before dulling
  • • Use maximum depth of cut practical
  • • Rigid machine setup critical
  • • Low cutting speeds with heavy feeds
  • • Plan tool paths to minimize passes

Tooling Specifications

  • • Carbide grades: C2 or C3 (tough substrate)
  • • Coatings: TiAlN, AlTiN, or multilayer
  • • Ceramics for finishing (Al₂O₃/TiC blend)
  • • Positive rake angles (10-20°)
  • • Large nose radius for strength
  • • Chip breaker geometry mandatory
  • • CBN tools for severe applications
Operation Recommended Parameters
Turning (Roughing) Speed: 30-60 SFM (9-18 m/min), Feed: 0.008-0.015 ipr, DOC: 0.125-0.250"
Turning (Finishing) Speed: 60-90 SFM (18-27 m/min), Feed: 0.004-0.008 ipr, DOC: 0.030-0.060"
Milling (Face/Slab) Speed: 40-80 SFM (12-24 m/min), Feed: 0.004-0.010 ipt, radial DOC 50-75% of cutter diameter
Milling (End) Speed: 50-100 SFM (15-30 m/min), Feed: 0.003-0.008 ipt, use climb milling
Drilling Speed: 15-30 SFM (4.5-9 m/min), Feed: 0.001-0.005 ipr, MANDATORY peck drilling
Threading Thread milling strongly preferred, single-point only as last resort at very low speeds
Coolant High-pressure flood coolant REQUIRED, sulfurized or extreme-pressure cutting oils

Machining Success Key: Hastelloy C-276 work hardens more severely than most superalloys. The work-hardened layer from previous passes must be removed completely on each subsequent pass. Use the maximum practical depth of cut to get below the work-hardened zone. Never allow the tool to rub or dwell.

Welding & Fabrication

Hastelloy C-276 has excellent weldability and can be readily welded using common fusion welding processes. The alloy's low carbon content (≤0.01%) minimizes carbide precipitation, ensuring the weld zone maintains corrosion resistance without post-weld heat treatment.

Recommended Processes

  • • GTAW (TIG) - Best for critical joints
  • • GMAW (MIG) - Production welding
  • • SMAW (Stick) - Field repairs
  • • SAW (Submerged Arc) - Heavy sections
  • • Plasma Arc Welding (PAW)
  • • Electron Beam & Laser - Precision

Filler Metal

  • • ERNiCrMo-4 (AWS A5.14) - Primary choice
  • • ENiCrMo-4 for SMAW
  • • Match base metal composition closely
  • • Ultra-low carbon filler essential
  • • Store in controlled humidity environment
  • • Clean thoroughly before use

Critical Welding Requirements

  • Cleanliness is Critical: Remove all oil, grease, marking inks, cutting fluids, and shop dirt
  • Use Argon Shielding: Pure argon or argon-helium mix for GTAW/GMAW
  • Backing Gas Required: Use for full penetration welds to prevent oxidation
  • Interpass Temperature: Keep below 150°C (300°F) to minimize heat input
  • No Preheat Required: Room temperature welding acceptable
  • Post-Weld Treatment: Generally not required due to low carbon content
  • Multi-Pass Welding: Keep weld pool small, use stringer beads

Weld Zone Corrosion Resistance

One of Hastelloy C-276's key advantages is that the weld zone maintains corrosion resistance equivalent to the base metal without post-weld heat treatment. The ultra-low carbon content prevents carbide precipitation during welding, eliminating the sensitization that occurs in higher-carbon nickel alloys.

Superior Corrosion Resistance

Hastelloy C-276 exhibits exceptional resistance to a wider variety of corrosive media than virtually any other commercial alloy. Its performance in both oxidizing and reducing environments, combined with outstanding resistance to localized corrosion, makes it the material of choice for the most demanding chemical processing applications.

Outstanding Resistance To:

  • • Sulfuric acid (all concentrations, temperatures)
  • • Hydrochloric acid (all concentrations)
  • • Phosphoric acid
  • • Acetic acid and acetic anhydride
  • • Formic acid
  • • Hypochlorite and chlorine solutions
  • • Wet chlorine gas
  • • Ferric and cupric chlorides
  • • Seawater and marine atmospheres
  • • Brine solutions
  • • Sour gas (H₂S, CO₂, moisture)

Localized Corrosion:

  • Pitting Resistance: PREN value >70
  • Crevice Corrosion: Excellent resistance in chlorides
  • Stress Corrosion Cracking: Outstanding immunity
  • Intergranular Attack: Resistant even when welded
  • Galvanic Corrosion: Performs well coupled with other alloys

PREN Formula: %Cr + 3.3(%Mo) + 16(%N)
Higher PREN = Better pitting resistance
C-276 typically achieves PREN of 70-75

Mixed Acid Environments

Hastelloy C-276 is particularly valued for its resistance to mixed acid environments where both oxidizing and reducing conditions exist simultaneously. This includes sulfuric acid contaminated with chlorides, mixed sulfuric-nitric-hydrochloric acids, and other complex chemical mixtures where conventional materials fail.

Important Limitations

  • • Not recommended for dry chlorine gas above 150°C (300°F)
  • • May be susceptible to crevice corrosion in highly oxidizing chloride solutions at elevated temperatures
  • • Stress corrosion cracking possible in extremely hot concentrated magnesium chloride (very rare conditions)
  • • Always test in actual service conditions for critical applications

Overview

Material Type
Nickel-Molybdenum-Chromium Superalloy
Primary Alloying
Ni-Mo-Cr-W
Condition
Solution Annealed
Weldability
Excellent
Corrosion Resistance
Superior (Best in Class)
Typical Forms
Plate, Sheet, Bar, Pipe, Tubing, Fittings

Standards & Designations

UNS
N10276
Werkstoff Nr.
2.4819
ASTM
B575, B619, B622
ASME
SB-575, SB-619
AMS
5750
AWS
A5.14 (ERNiCrMo-4)

Key Corrosion Metrics

PREN Value
70-75
Exceptional pitting resistance
Critical Pitting Temp (CPT)
115°C+
In 6% FeCl₃ solution
Stress Corrosion Cracking
Immune
Chloride environments

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